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Document ID ca-gcdwqgtd-2015-04-24-7 Title Guidelines for Canadian Drinking Water Quality: Guideline Technical Document – Selenium URL https://www.canada.ca/en/health-canada/services/publications/healthy-living/guidelines-canadian-drinking-water-quality-guideline-technical-document-selenium/guidelines-canadian-drinking-water-quality-guideline-technical-document-selenium-page-8.html Jurisdiction /ca Subdomain(s) Drinking water, Water treatment process Language en Status completed Analyzed at 2026-03-18 16:16:53.488323+00:00 Relevance Technical guidance on selenium removal technologies and treatment efficiencies.

Q Qualitative Requirements (29)

Req ID Category Intent Legal Status Name Subdomain(s) Context Conditions Confidence
#Q001designtreatmentrecommendedIon Exchange Pilot Studiesdrinking waterPilot studies should be conducted in order to verify the effectiveness of ion exchange technology for site-specific water quality.When considering ion exchange technology for selenium removal.high
#Q002designhealthrecommendedIon Exchange Resin Selectiondrinking waterTo minimize nitrosamine formation, attention should be paid when selecting strong-base ion exchange resins (Kimoto et al., 1980; Najm and Trussell, 2001).When selecting strong-base ion exchange resins.high
#Q003treatmentoperationalmandatoryRO Feed Water Pretreatmentdrinking waterA pretreatment of the feed water is required to prevent scaling and fouling of the RO membranes.When using reverse osmosis (RO) membrane systems.high
#Q004treatmenttreatmentmandatoryRO Product Water Post-treatmentdrinking waterThe product water typically requires post-treatment, consisting of pH and alkalinity adjustments.When using reverse osmosis (RO) membrane systems.high
#Q005treatmenttreatmentmandatoryRO Post-treatment Corrosion Controldrinking waterIn most cases, post-treatment corrosion control measures need to be undertaken.Following reverse osmosis (RO) treatment.high
#Q006designoperationalmandatoryActivated Alumina Chemical Handling Considerationdrinking waterUtilities need to consider the chemical handling and disposal requirements prior to selecting this treatment technology (U.S. EPA, 1989, 1998).Prior to selecting activated alumina treatment technology.high
#Q007designtreatmentmandatoryElectrodialysis Pilot Testingdrinking waterUtilities planning to utilize electrodialysis for the reduction of selenium, total dissolved solids and other trace metals would require pilot plant testing of the feed water in order to verify the effectiveness of selenium removal.Utilities planning to utilize electrodialysis.high
#Q008treatmenttreatmentrecommendedFerric Oxide Media pH Adjustmentdrinking waterAt pH values greater than 8.0 to 8.5, pH adjustment is recommended to ensure adsorption capacity is maintained.When using ferric oxide media at pH values greater than 8.0 to 8.5.high
#Q009treatmentoperationalrecommendedAvoidance of Additional Treatment on Municipal Waterdrinking waterGenerally, it is not recommended that drinking water treatment devices be used to provide additional treatment to municipally treated drinking water.For municipally treated drinking water at the residential scale.high
#Q010monitoringtreatmentrecommendedWell Water Pre-installation Testingdrinking waterBefore a treatment device is installed, the well water should be tested to determine general water chemistry and to verify the concentration of selenium.Before installing a residential treatment device on a private well.high
#Q011monitoringtreatmentrecommendedTesting for Competing Ionsdrinking waterThe testing should also include assessing the presence and concentration of competing ions (e.g., sulphate, nitrate, chloride) and organic matter in the water, which could interfere with selenium removal.Before installing a residential treatment device on a private well.high
#Q012treatmentoperationalmandatoryDevice Maintenance and Replacementdrinking waterDevices can lose removal capacity through usage and time and need to be maintained and/or replaced.Over the operational lifespan of residential drinking water treatment devices.high
#Q013operationaloperationalrecommendedConsumer Verification of Component Longevitydrinking waterConsumers should verify the expected longevity of the components in their treatment device as per the manufacturer's recommendations.When using residential drinking water treatment devices.high
#Q014designhealthrecommendedUse of Certified Devicesdrinking waterHealth Canada does not recommend specific brands of drinking water treatment devices, but it strongly recommends that consumers use devices that have been certified by an accredited certification body as meeting the appropriate NSF/ANSI drinking water treatment unit standards.When selecting residential drinking water treatment devices.high
#Q015administrativeoperationalmandatoryAccreditation of Certification Organizationsdrinking waterCertification organizations provide assurance that a product conforms to applicable standards and must be accredited by the Standards Council of Canada (SCC).For certification organizations verifying NSF/ANSI standards in Canada.high
#Q016treatmentoperationalguidanceResidential RO Feed Water Pretreatmentdrinking waterA consumer may need to pretreat the influent water to reduce fouling and extend the service life of the membrane.When using reverse osmosis (RO) drinking water treatment systems at residential scale.high
#Q017operationaloperationalmandatoryIon Exchange Resin Regenerationdrinking waterOnce the resin has reached its capacity (i.e., when all the resin sites are occupied by the contaminant ion), the resin must be regenerated to reverse the process.Once ion exchange resin capacity is reached.high
#Q018operationaloperationalmandatoryActivated Alumina Bed Regenerationdrinking waterWhen adsorption sites on the activated alumina surface become filled, the bed must be regenerated.When adsorption sites on activated alumina are filled.high
#Q019operationaloperationalmandatoryActivated Alumina Operational Considerationsdrinking waterWhen employing activated alumina technology, operational issues that must be considered include the degradation of activated alumina through the regeneration process and the fouling of the activated alumina bed, resulting in an increase in headloss across the media bed.When employing activated alumina technology.high
#Q020operationalreportingmandatoryRO Concentrate Disposaldrinking waterthe concentrate discharge must be disposed of appropriately.Disposal of reject water/brine from RO systems.high
#Q021designhealthmandatoryNSF/ANSI Standard 61 Selenium Leaching Limitdrinking waterWhen materials are certified to the standard, the concentration of selenium must not exceed the single product allowable concentration of 0.005 mg/L (NSF/ANSI, 2011a).For materials certified to NSF/ANSI Standard 61.high
#Q022designtreatmentmandatoryNSF/ANSI Residential Device Performance Requirementdrinking waterDrinking water treatment devices certified to NSF/ANSI Standards 53, 58 and 62 specifically for selenium removal, must be capable of reducing the concentration of selenium in water from an influent (challenge) concentration of 0.1 mg/L (added as 0.05 mg/L for Se(IV) and 0.05 mg/L for Se(VI)) to a maximum final (effluent) concentration of 0.05 mg/L (NSF/ANSI, 2009a,b, 2011b).When devices are certified specifically for selenium removal under NSF/ANSI 53, 58, or 62.high
#Q023designtreatmentmandatoryNSF/ANSI 62 TDS Surrogate Performance Requirementdrinking waterTreatment devices certified to NSF/ANSI Standard 62 using TDS as a surrogate, must achieve a minimum TDS reduction of 99.0% from an influent (challenge) concentration of 1000 mg/L(NSF/ANSI, 2009b).When devices are certified using TDS as a surrogate under NSF/ANSI 62.high
#Q024prohibitiontreatmentmandatorySmall System BAT Restrictiondrinking waterConventional coagulation/filtration and lime softening processes are not defined as BATs for small systems unless these treatment processes are currently in place (U.S. EPA, 1991c).For small water systems evaluating Best Available Technologies (BATs) for selenium removal.high
#Q025designtreatmentguidelineResidential RO Point-of-Use Limitationdrinking waterRO systems certified to NSF/ANSI Standard 58 (Reverse Osmosis Drinking Water Treatment Systems) are intended for point-of-use installation only.When using residential RO systems certified to Standard 58.high
#Q026designtreatmentguidelineResidential Distillation Point-of-Use Limitationdrinking waterDistillation systems certified to NSF/ANSI Standard 62 (Drinking Water Distillation Systems) are also intended for point-of-use installation only.When using residential distillation systems certified to Standard 62.high
#Q027designtreatmentrecommendedIon Exchange Se(IV) Speciation Considerationdrinking waterThe ion exchange behaviour of the monovalent biselenite form (HSeO3−) and divalent form (SeO32−) should be considered, as the monovalent anion is less preferred than the divalent anion (Maneval et al., 1985).When considering the ion exchange removal of Se(IV).high
#Q028operationaloperationalmandatoryManganese Greensand Bed Regenerationdrinking waterWhen the manganese greensand bed is exhausted, the bed is regenerated to restore its oxidizing capacity.When using manganese greensand filtration and the bed is exhausted.high
#Q029operationaloperationalmandatoryActivated Alumina Surveillance and Maintenancedrinking waterThe technology requires adequate surveillance and maintenance, including the use of concentrated acids (sulphuric acid or hydrochloric acid) and base (sodium hydroxide) for regeneration of activated alumina.When employing activated alumina technology.high

P Quantitative Requirements (6)

Req ID Category Intent Legal Status Name Subdomain(s) Limit Type Limit Value Context Conditions Confidence
#P001chemicaltreatmentmandatorySelenium influent challenge concentrationdrinking waterrequirement0.1 mg/LDrinking water treatment devices certified to NSF/ANSI Standards 53, 58 and 62 specifically for selenium removaladded as 0.05 mg/L for Se(IV) and 0.05 mg/L for Se(VI)high
#P002chemicaltreatmentmandatorySelenium maximum final effluent concentrationdrinking waterMAC<= 0.05 mg/LDrinking water treatment devices certified to NSF/ANSI Standards 53, 58 and 62 specifically for selenium removalmust be capable of reducing the concentration of selenium in water to a maximum final (effluent) concentrationhigh
#P003physicaltreatmentmandatoryTotal dissolved solids (TDS) minimum reductiondrinking waterrequirement>= 99.0 %Treatment devices certified to NSF/ANSI Standard 62 using TDS as a surrogatehigh
#P004physicaltreatmentmandatoryTotal dissolved solids (TDS) influent challenge concentrationdrinking waterrequirement1000 mg/LTreatment devices certified to NSF/ANSI Standard 62 using TDS as a surrogatehigh
#P005chemicalhealthmandatorySelenium single product allowable concentrationdrinking waterMAC<= 0.005 mg/LNSF/ANSI Standard 61 (Drinking Water System Components--Health Effects) limits the leaching of selenium into drinking waterWhen materials are certified to the standardhigh
#P006chemicaltreatmentguidanceSelenium treatment goaldrinking watertreatment_goal0.01 mg/LBenchmark effluent concentration used to evaluate the effectiveness and breakthrough capacity of various municipal treatment technologies.Applied as the target effluent limit for performance testing of technologies like Ion Exchange, Activated Alumina, and Manganese Greensand Filtration.high

D Definitions (18)

Req ID Category Name Context Confidence
#D001BATsbest available technologieshigh
#D002SBAstrong base anionhigh
#D003Chromatographic peakingChromatographic peaking is a process in which less preferred ions will be concentrated in the column and will, at some time, exit the column in concentrations exceeding their influent concentrations.medium
#D004EBCTempty bed contact timehigh
#D005Mgdmillion gallons per dayhigh
#D006breakthrough capacitythe amount of selenium adsorbed per litre of activated alumina before the effluent selenium concentration exceeded the treatment goal of 0.01 mg/L.high
#D007GFHGranular ferric hydroxidehigh
#D008ROreverse osmosishigh
#D009SCCStandards Council of Canadahigh
#D010TDStotal dissolved solidshigh
#D011Co-precipitationinvolves sorption/inclusion of contaminants to an actively precipitating substrate, resulting in the formation of mixed solid-phase.high
#D012Ion exchangea physicochemical process in which there is an exchange of ions in the raw water with ions within the solid phase of a resin.high
#D013contaminant breakthroughfinished water concentrations that increasehigh
#D014Activated aluminaa physicochemical process by which ions in the feed water are sorbed to the oxidized activated alumina surface.high
#D015Secondary adsorptionoccurs as a joint adsorption of anions with multivalent cations or as a joint adsorption of cations with multivalent anionshigh
#D016Electrodialysisan electrochemical separation process in which charged species from water are transported through semipermeable membranes under the influence of an electric potential.high
#D017Greensandglauconite, a green, iron-rich mineral that has ion exchange properties.high
#D018Biological treatmentuses microorganisms to reduce, oxidize or eliminate groundwater contaminants, either as the sole treatment technique or combined with other conventional physicochemical processeshigh